Detailed Insight into the CZTS/CdS Interface Modification by Air Annealing in Monograin Layer Solar Cells

نویسندگان

چکیده

Relatively fast achievements in the kesterite solar cell technology have been made over last decade, but experimental efficiency is still ?13%. One proposed reason an inappropriate band alignment with Cu2ZnSnS4 (CZTS) and CdS that results strong interface recombination losses. Results of this work show temperature duration air annealing CZTS/CdS heterojunction are essential for device performance. Soft slightly improved due to elemental intermixing at interface. On other hand, extended increased absorber gap energy, resulting higher VOC values, indicating Cu–Zn ordering CZTS structure, which also could be expected a beneficial influence on However, analysis revealed surface layer was Cu-rich, providing reduction The effect defects analyzed by capacitance–frequency–voltage (C–V–f) combined SCAPS simulations. C–V–f-based loss maps showed modifies density distribution asymmetrical states interface, becomes fully symmetrical longer times 200 °C.

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ژورنال

عنوان ژورنال: ACS applied energy materials

سال: 2021

ISSN: ['2574-0962']

DOI: https://doi.org/10.1021/acsaem.1c02186